Reversible C=C Bond Activation by an Intramolecularly Coordinated Antimony(I) Compound.

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ID: 3986
2019
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Ranked #80 of 117 articles by views in Chemistry (Weinheim an der Bergstrasse, Germany)

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Abstract
The reaction of N,C,N-chelated stibinidene ArSb (1) (Ar = C6H3-2,6-(CH=NtBu)2) with selected N-alkyl/aryl-maleimides RN(C(O)CH)2 (R = Me, tBu, Ph) gave the addition products with bridged bicyclic [2.2.1] structure containing antimony atom at bridgehead position, fused with 6-membered benzene and 5-membered N-alkyl/aryl-pyrrolidine ring. These compounds were completely characterized. More importantly, additional studies showed that these reactions are reversible in solution, thereby representing an unprecedented reversible activation of a C=C bond by the antimony(I) compound 1.
Reference Key
koenkov2019reversiblechemistry Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Monika Kořenková, Martin Hejda, Milan Erben, Robert Jirásko, Roman Jambor, Aleš Růžička, Elena Rychagova, Sergey Ketkov, Libor Dostál
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Journal Chemistry (Weinheim an der Bergstrasse, Germany)
Year 2019
DOI
10.1002/chem.201902968
URL
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