Interplay of arene radical cations with anions and fluorinated alcohols in hole catalysis

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ID: 3967
2019
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Abstract
Fluorinated solvents such as hexafluoroisopropanol (HFIP) are often useful in reactions involving radical cations. Here the role of HFIP in photoredox and electrochemical Diels-Alder reactions is explored experimentally and theoretically, and attributed to solvation of anions to reduce their nucleophilicity.
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shida2019interplaycommunications Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Shida, Naoki;Imada, Yasushi;Nagahara, Shingo;Okada, Yohei;Chiba, Kazuhiro;
Journal Communications chemistry
Year 2019
DOI
DOI not found
URL
http://link.springer.com/article/10.1038/s42004-019-0125-4
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