Interplay of arene radical cations with anions and fluorinated alcohols in hole catalysis
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2019
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Abstract
Fluorinated solvents such as hexafluoroisopropanol (HFIP) are often useful in reactions involving radical cations. Here the role of HFIP in photoredox and electrochemical Diels-Alder reactions is explored experimentally and theoretically, and attributed to solvation of anions to reduce their nucleophilicity.
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| Authors | Shida, Naoki;Imada, Yasushi;Nagahara, Shingo;Okada, Yohei;Chiba, Kazuhiro; |
| Journal | Communications chemistry |
| Year | 2019 |
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