Acyl-isothiocyanates as efficient thiocyanate transfer reagents.

Clicks: 278
ID: 3624
2009
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Abstract
An unprecedented transfer of a thiocyanate (-SCN) group from aroyl/acyl isothiocyanate to alkyl or benzylic bromide is observed in the presence of a tertiary amine. This process is most effective when the bromomethyl proton is less acidic, while the presence of a more acidic proton gives 1,3-oxathiol-2-ylidine and other related products.
Reference Key
palsuledesai2009acylisothiocyanatesorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Palsuledesai, Charuta C;Murru, Siva;Sahoo, Santosh K;Patel, Bhisma K;
Journal Organic letters
Year 2009
DOI
10.1021/ol901561j
URL
Keywords Keywords not found

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