Tandem arylation and regioselective allylic etherification of 2,3-allenol via Pd/B cooperative catalysis.

Clicks: 389
ID: 34811
2019
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Abstract
An efficient method for the construction of arylated allylic ethers was developed via three-component tandem arylation and allylic etherification of 2,3-allenol with aryl iodides and alcohols. In the cooperative catalytic system of a palladium complex and triethylborane, the process allows rapid access to functionalized 1-arylvinylated 1,2-diol derivatives in good to high yields with complete branch-selectivities. The synthetic utility of the present process was demonstrated by the late-stage functionalization of a drug molecule, the gram-scale synthesis and the elaboration of the products.
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li2019tandemorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Li, Hongfang;Li, Tao;Hsueh, Yu Jen;Wu, Xue;Xu, Feng;Zhang, Yong Jian;
Journal Organic & biomolecular chemistry
Year 2019
DOI
10.1039/c9ob01792e
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