Hydrolysis and Hydrazinolysis of Isatin-Based Ald- and Ketazines
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ID: 33169
2015
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Abstract
The hydrolysis of isatin aldazine 4a–d afforded the unexpected 3,3′-(hydrazine-1,2-diylidene)bis(indolin-2-one) (5) and 1,2-di(arylidene)hydrazines 6a–d through dual hydrolysis of 4a–d. A mechanism to explain the formation of 5 and 6a–d was proposed. In addition, the hydrazinolysis of 4a–d yielded 3-hydrazonoindolin-2-one (2) and 1,2-di(arylidene)hydrazines 6a–d instead of hydrazones 17a–d, while hydrazinolysis of isatin ketazine 5 gave the expected 3-hydrazonoindolin-2-one (2). These results indicated the ability of the title compounds for unusual hydrolysis and hydrazinolysis reactions.
| Reference Key |
ibrahim2015hydrolysisjournal
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| Authors | Ibrahim, Hany S.;Abdelhadi, Soha R.;Abdel-Aziz, Hatem A.; |
| Journal | journal of chemistry |
| Year | 2015 |
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| Keywords | Keywords not found |
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