Oxidative Cross-Coupling of Trans -1,2-Dizincioalkenes With Alkylzincs Through Pd/Zn Ligand-Scrambling
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ID: 321769
2026
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Abstract
Abstract 1,2-Dimetalloalkenes are versatile precursors for the stereoselective synthesis of multi-substituted alkenes. We have recently reported the reductive anti-dizincation of alkynes using sodium metal and zinc chloride. Here we report that trans-1,2-dizincioalkenes underwent a palladium-catalyzed oxidative cross-coupling with alkylzincs with the aid of 2,4,6-trimethoxyiodobenzene to yield anti-1,2-dialkylated alkenes stereoselectively. Mechanistic investigations suggest that the catalytic cycle involves a palladium-zinc ligand-scrambling process between organopalladium and organozinc species and subsequent reductive elimination to form an alkenyl-alkyl bond.
| Reference Key |
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| Authors | H Yamaguchi, Takashi Kurogi, Hideki Yorimitsu |
| Journal | bulletin of the chemical society of japan |
| Year | 2026 |
| DOI |
10.1093/bulcsj/uoag104
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| URL | |
| Keywords | Keywords not found |
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