Generation of Functionalized Acetylides for C-C Bond Formation
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ID: 315505
2026
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Abstract
Abstract Effective preparation and addition reactions of highly functionalized acetylides are described. While classical procedures with butyllithium or Grignard reagents often suffer from functional group limitations, the current procedure employs the turbo-Grignard reagent and bromoalkynes possessing epoxide, acetate, and chloride functional groups for acetylide formation. The addition reactions with the resulting acetylides proceeded in the presence of catalytic ZnCl2. This procedure is a promising alternative to the classical approaches due to its high functional group tolerance.
| Reference Key |
openalex_W7163212370
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| Authors | Koshiro Kudo, Riku Yatabe, Hyuga Okumura, Nurcahyo Iman Prakoso, Tatsuya Morozumi, Taiki Umezawa |
| Journal | bulletin of the chemical society of japan |
| Year | 2026 |
| DOI |
10.1093/bulcsj/uoag077
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| URL | |
| Keywords | Keywords not found |
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