Synthesis of Boranils by Iodide-Mediated Demethylative Borylation and Their Properties
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ID: 315450
2026
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Abstract
Abstract Boranils, difluoroboron complexes with imine and phenoxy moieties, were synthesized by iodide-promoted demethylative borylation. The use of appropriate amounts of BF3•OEt2, Bu4NI, and Et3N enabled the highly efficient synthesis of boranils. Boranils containing heteroaromatics and highly π-extended boranils were also readily obtained by this method. Their physical properties were studied and the properties were consistent with those calculated by DFT calculations.
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| Authors | Koichi Mitsudo, Ryo Magata, Eisuke Sato, Tomoya Nakamura, Atsushi Wakamiya, Seiji Suga |
| Journal | bulletin of the chemical society of japan |
| Year | 2026 |
| DOI |
10.1093/bulcsj/uoag070
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| URL | |
| Keywords | Keywords not found |
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