Nitrogen substrate–dependent nitrous oxide cycling in salt marsh sediments

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ID: 298860
2015
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Abstract
Nitrous oxide (N 2 O) is important to Earth's climate because it is a strong absorber of radiation and an important ozone depletion agent. Increasing anthropogenic nitrogen input into the marine environment, especially to coastal waters, has led to increasing N 2 O emissions. Identifying the nitrogen compounds that serve as substrates for N 2 O production in coastal waters reveals important pathways and helps us understand their control by environmental factors. In this study, sediments were collected from a long-term fertilization site in Great Sippewissett Marsh, Falmouth, Massachusetts. The 15 N tracer incubation time course experiments were conducted and analyzed for potential N 2 O production and consumption rates. The two nitrogen substrates of N 2 O production, ammonium and nitrate, correspond to the two production pathways, nitrification and denitrification, respectively. When measurable nitrate was present, despite ambient high ammonium concentrations, denitrification was the major N 2 O production pathway. When nitrate was absent, ammonium became the dominant substrate for N 2 O production, via nitrification and coupled nitrification-denitrification. Net N 2 O consumption was enhanced under low oxygen and nitrate conditions. N 2 O production and consumption rates increased with increasing levels of nitrogen fertilization in long-term experimental plots. These results indicate that increasing anthropogenic nitrogen input to salt marshes can stimulate sedimentary N 2 O production via both nitrification and denitrification, whereas episodic oxygen depletion results in net N 2 O consumption.
Reference Key
openalex_W2776278656 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Qixing Ji, Andrew R. Babbin, Xuefeng Peng, Jennifer L. Bowen, Bess B. Ward
Journal journal of marine research
Year 2015
DOI
10.1357/002224015815848820
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