Organometallic complexes for nonlinear optics, 47 - synthesis and cubic optical nonlinearity of a stilbenylethynylruthenium dendrimer.

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ID: 2830
2010
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Abstract
The synthesis of the 1st generation dendrimer 1,3,5-{trans-[Ru(C≡C-3,5-(trans-[Ru(C≡CPh)(dppe)(2) (C≡CC(6) H(4) -4-(E)-CHCH)])(2) C(6) H(3) )(dppe)(2) (C≡CC(6) H(4) -4-(E)-CHCH)]}(3) C(6) H(3) proceeds by a novel route that features Emmons-Horner-Wadsworth coupling of 1,3,5-C(6) H(3) (CH(2) PO(OEt)(2) )(3) with trans-[Ru(C≡CC(6) H(4) -4-CHO)Cl(dppe)(2) ] and 1-I-C(6) H(3) -3,5-(CH(2) PO(OEt)(2) )(2) with trans-[Ru(C≡CPh)(C≡CC(6) H(4) -4-CHO)(dppe)(2) ] as key steps. The stilbenylethynylruthenium dendrimer is much more soluble than its ethynylated analog 1,3,5-{trans-[Ru(C≡C-3,5-(trans-[Ru(C≡CPh)(dppe)(2) (C≡CC(6) H(4) -4-C≡C)])(2) C(6) H(3) )(dppe)(2) (C≡CC(6) H(4) -4-C≡C)]}(3) C(6) H(3) and, in contrast to the ethynylated analog, is a two-photon absorber at telecommunications wavelengths.
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jeffery2010organometallicmacromolecular Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Christopher J Jeffery, Marie P Cifuentes, Gulliver T Dalton, T Christopher Corkery, Michael D Randles, Anthony C Willis, Marek Samoc, Mark G Humphrey
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Journal Macromolecular rapid communications
Year 2010
DOI
10.1002/marc.200900859
URL
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