Donor-π-Acceptor Polymer with Alternating Triarylborane and Triphenylamine Moieties.

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ID: 2829
2010
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Abstract
A luminescent main chain donor-π-acceptor-type polymer (4) was prepared via organometallic polycondensation reaction followed by post modification. With both electron-rich amine and electron-deficient borane moieties embedded in the main chain, 4 exhibits an interesting ambipolar character: it can be reduced and oxidized electrochemically at moderate potentials and shows a strong solvatochromic effect in the emission spectra. Complexation studies show that 4 selectively binds to fluoride and cyanide; quantitative titration with cyanide reveals a two-step binding process.
Reference Key
li2010donoracceptormacromolecular Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Li, Haiyan;Jäkle, Frieder;
Journal Macromolecular rapid communications
Year 2010
DOI
10.1002/marc.200900932
URL
Keywords Keywords not found

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