Silicone Resin Applications for Ceramic Precursors and Composites

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ID: 2822
2010
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Ranked #267 of 812 articles by views in Materials (Basel, Switzerland)

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Abstract
This article reviews the applications of silicone resins as ceramic precursors. The historical background of silicone synthesis chemistry is introduced to explain the production costs and supply availability of various silicones. Thermal degradation processes of silicones are classified in terms of the main chain structure and cyclic oligomer expulsion process, which determine the resulting ceramic yield and the chemical composition. The high temperature decomposition of Si-O-C beyond 1,400 °C in an inert atmosphere and formation of a protective silica layer on material surfaces beyond 1,200 °C in an oxidative atmosphere are discussed from the viewpoints of the wide chemical composition of the Si-O-C materials. Applications of the resins for binding agents, as starting materials for porous ceramics, matrix sources with impregnation, fiber spinning and ceramic adhesions are introduced. The recent development of the process of filler or cross-linking agent additions to resin compounds is also introduced. Such resin compounds are useful for obtaining thick coatings, MEMS parts and bulk ceramics, which are difficult to obtain by pyrolysis of simple organometallic precursors without additives.
Reference Key
narisawa2010siliconematerials Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Narisawa, Masaki;
Journal Materials (Basel, Switzerland)
Year 2010
DOI
DOI not found
URL
http://www.mdpi.com/1996-1944/3/6/3518/
Keywords Keywords not found

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