Discrete Thermodynamics of Chemical Equilibria
Clicks: 68
ID: 281871
2008
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This
article has not been analysed, so there is no overall score —
reader engagement is measured and shown alongside.
Reader Engagement
Star Article
20.1
/100
68 views
12 readers
AI Quality Assessment
Not analyzed
Readership in this journal
StarRanked #432 of 803 articles by views in arXiv
Most read
Least read
Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 803 in total.
Mint this article as an NFT
Not yet mintedCreate a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.
5
SUSD
one-off · no wallet required
Abstract
The paper sets forth comprehensive basics of Discrete Thermodynamics of
Chemical Equilibria (DTD), developed by the author during the last decade and
spread over series of publications. Based on the linear equations of
irreversible thermodynamics, De Donder's definition of the thermodynamic force,
and the Le Chatelier principle, DTD brings forward a notion of chemical
equilibrium as a balance of internal and external thermodynamic forces, acting
against a chemical system. The basic expression of DTD is a logistic map that
ties together energetic characteristics of the chemical transformation in the
system, its deviation from true thermodynamic equilibrium, and the sum of
thermodynamic forces, causing that deviation. System deviation from
thermodynamic equilibrium is the major variable of the theory. Solutions to the
basic map define the chemical system domain of states comprising bifurcation
diagrams with four areas, from true thermodynamic equilibrium to chaos, having
specific distinctive meaning for chemical systems. The theory is derived from
the currently recognized ideas of chemical thermodynamics and binds classical
and contemporary thermodynamics of chemical equilibria into a unique concept.
DTD opens new opportunities in understanding and analysis of equilibria in
chemical systems. Some new results, included in the paper, have never been
published before.
| Reference Key |
zilbergleyt2008discrete
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | B. Zilbergleyt |
| Journal | arXiv |
| Year | 2008 |
| DOI |
DOI not found
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.