W-Shaped π-Extended Double Undecabenzo[7]helicene.

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ID: 279572
2024
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Abstract
A chiral W-shaped fully π-extended double [7]helicene () has been synthesized and fully characterized. It displays fluorescence emission (λ = 636 nm) with a quantum yield (Φ) of 0.10. In comparison to its X-shaped and monomict π-extended [7]helicene analogues, enantiopure W-shaped exhibited superior chiral optical characteristics, including distinct circular dichroism signals from 400 to 650 nm, a good dissymmetric emission factor || of 4 × 10, and a circularly polarized luminescence brightness value of 42 M cm.
Reference Key
shen2024wshapedorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Shen, Yun-Jia;Peng, Li-Jun;Diao, Li-Na;Yao, Nai-Te;Chen, Wen-Kai;Yang, Yang;Qiu, Meng;Zhu, Wen-Xiu;Li, Xuan;Wang, Xing-Yu;Gong, Han-Yuan;
Journal Organic letters
Year 2024
DOI
10.1021/acs.orglett.4c02093
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