ON THE PECULIARITIES OF THE RING CONTRACTION REACTIONS OF HOMODRIMANES VIA ACID MEDIATED EPOXIDE REARRANGEMENT

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ID: 278167
2011
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Abstract
A selective rearrangement of a epoxy-homodrimanic substrate is described. Using fluorosulfonic acid at low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride-diethyl ether at r.t. selectively brings about angular methyl migration.
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Authors Kulciţki, Veaceslav;Sîrbu, Tatiana;Ungur, Nicon;
Journal chemistry journal of moldova: general, industrial and ecological chemistry
Year 2011
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