ON THE PECULIARITIES OF THE RING CONTRACTION REACTIONS OF HOMODRIMANES VIA ACID MEDIATED EPOXIDE REARRANGEMENT

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ID: 278167
2011
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Abstract
A selective rearrangement of a epoxy-homodrimanic substrate is described. Using fluorosulfonic acid at low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride-diethyl ether at r.t. selectively brings about angular methyl migration.
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Authors Kulciţki, Veaceslav;Sîrbu, Tatiana;Ungur, Nicon;
Journal chemistry journal of moldova: general, industrial and ecological chemistry
Year 2011
DOI
DOI not found
URL
http://www.cjm.asm.md/sites/default/files/article_files/Kulcitki%20110-112.pdf
Keywords
chemistry Biotechnology Pediatrics physics geography (general) neurosciences. biological psychiatry. neuropsychiatry mathematics crystallography international relations auxiliary sciences of history history of civilization general. including alchemy

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