2-Hydroxy-imino-1-phenyl-ethanone thio-semicarbazone monohydrate.

Clicks: 124
ID: 276948
2008
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Abstract
In the title thio-semicarbazone derivative, C(9)H(10)N(4)OS·H(2)O, intra-molecular N-H⋯N hydrogen bonds result in the formation of two nearly coplanar five- and six-membered rings, which are also almost coplanar with the adjacent phenyl ring. The oxime group has an E configuration and is involved in inter-molecular O-H⋯O hydrogen bonding as a donor. In the crystal structure, intra-molecular O-H⋯S and N-H⋯N and inter-molecular O-H⋯O and N-H⋯S hydrogen bonds generate edge-fused R(2) (2)(8) and R(4) (1)(11) ring motifs. The hydrogen-bonded motifs are linked to each other to form a three-dimensional supra-molecular network.
Reference Key
sarikavakli20082hydroxyimino1phenylethanoneacta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Sarıkavaklı, Nursabah;Babahan, Iknur;Sahin, Ertan;Hökelek, Tuncer;
Journal Acta crystallographica. Section E, Structure reports online
Year 2008
DOI
10.1107/S1600536808004947
URL
Keywords
1,4-phenylenediamine pyrrole-2-carboxaldehyde self assembled dithiocarbamate transition metal complexes

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