[3 + 3]-Cycloaddition of α-Diazocarbonyl Compounds and N-Tosylaziridines: Synthesis of Polysubstituted 2 H-1,4-Oxazines through Synergetic Catalysis of AgOTf/Cu(OAc).
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2019
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Abstract
An impressive and new [3 + 3]-cycloaddition of α-diazocarbonyl compounds with N-tosylaziridines via synergetic catalysis of AgOTf and Cu(OAc) has been well described, which offers efficient access to highly substituted 2 H-1,4-oxazine derivatives. A variety of α-diazocarbonyl compounds and N-tosylaziridines were compatible substrates with convenient operations under mild reaction conditions.
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| Authors | Fang, Shangwen;Zhao, Yanwei;Li, Haiyan;Zheng, Yonggao;Lian, Pengcheng;Wan, Xiaobing; |
| Journal | Organic letters |
| Year | 2019 |
| DOI |
10.1021/acs.orglett.9b00632
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