One-Pot Transformation of Hypervalent Iodines into Diversified Phenoxazine Analogues as Promising Photocatalysts.

Clicks: 266
ID: 275492
2021
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Abstract
A facile and efficient quinoline-fused 4-benzo[][1,4]oxazine has been successfully fabricated through an oxidative -arylation, Pd-catalyzed double -arylation of 4-hydroxyquinoline derivatives and trivalent aryl iodides. Diversified fused heterocycles could be easily constructed in overall high isolated yields with great substrate scope. The afforded heteroatom-"doped" phenoxazine demonstrated high molar absorptivities and excellent stability and redox reversibility. These phenoxazine analogues therefore could be utilized as promising catalysts in the photoredox catalyzed perfluoroalkylation of heteroarenes and photopromoted radical polymerization (OATRP).
Reference Key
cheng2021onepotthe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Cheng, Jiajia;Huang, Liangsen;Xiao, Hongxiang;Jiang, Shulin;
Journal The Journal of organic chemistry
Year 2021
DOI
10.1021/acs.joc.1c01883
URL
Keywords
X-ray crystallography Mycobacterium tuberculosis tuberculosis drug discovery cyp121

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