Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor

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2017
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Abstract
Myoglobin has recently emerged as a promising biocatalyst for catalyzing carbene-mediated cyclopropanation, a synthetically valuable transformation not found in nature. Having naturally evolved for binding dioxygen, the carbene transferase activity of this metalloprotein is severely inhibited by it, …
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Authors Sreenilayam G;Moore EJ;Steck V;Fasan R;;
Journal ACS catalysis
Year 2017
DOI
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http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=PubMed&dopt=Abstract&list_uids=29576911
Keywords
National Center for Biotechnology Information NCBI NLM MEDLINE pubmed abstract nih national institutes of health national library of medicine pmid:29576911 pmc5863724 doi:10.1021/acscatal.7b02583 gopeekrishnan sreenilayam eric j moore rudi fasan

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