Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor

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ID: 273853
2017
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Abstract
Myoglobin has recently emerged as a promising biocatalyst for catalyzing carbene-mediated cyclopropanation, a synthetically valuable transformation not found in nature. Having naturally evolved for binding dioxygen, the carbene transferase activity of ...
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Authors Gopeekrishnan Sreenilayam, Eric J. Moore, Viktoria Steck, Rudi Fasan;Gopeekrishnan Sreenilayam;Eric J. Moore;Viktoria Steck;Rudi Fasan;
Journal ACS catalysis
Year 2017
DOI
10.1021/acscatal.7b02583
URL
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5863724
Keywords
National Center for Biotechnology Information NCBI NLM MEDLINE pubmed abstract nih national institutes of health national library of medicine pmid:29576911 pmc5863724 doi:10.1021/acscatal.7b02583 gopeekrishnan sreenilayam eric j moore rudi fasan

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