Visual Identification of Light-Driven Breakage of the Silver-Dithiocarbamate Bond by Single Plasmonic Nanoprobes - Scientific Reports

Clicks: 175
ID: 271741
2015
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Star

Ranked #1,346 of 1,628 articles by views in Scientific reports

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 1,628 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Insight into the nature of metal-sulfur bond, a meaningful one in life science, interface chemistry and organometallic chemistry, is interesting but challenging. By utilizing the localized surface plasmon resonance properties of silver nanoparticles, herein we visually identified the photosensitivity of silver-dithiocarbamate (Ag-DTC) bond by using dark field microscopic imaging (iDFM) technique at single nanoparticle level. It was found that the breakage of Ag-DTC bond could be accelerated effectively by light irradiation, followed by a pH-dependent horizontal or vertical degradation of the DTC molecules, in which an indispensable preoxidation process of the silver was at first disclosed. These findings suggest a visualization strategy at single plasmonic nanoparticle level which can be excellently applied to explore new stimulus-triggered reactions and might also open a new way to understand traditional organic reaction mechanisms.
Reference Key
fei2015scientificvisual Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Gao, Peng Fei;Yuan, Bin Fang;Gao, Ming Xuan;Li, Rong Sheng;Ma, Jun;Zou, Hong Yan;Li, Yuan Fang;Li, Ming;Huang, Cheng Zhi;Gao, Peng Fei;Yuan, Bin Fang;Gao, Ming Xuan;Li, Rong Sheng;Ma, Jun;Zou, Hong Yan;Li, Yuan Fang;Li, Ming;Huang, Cheng Zhi;
Journal Scientific reports
Year 2015
DOI
doi:10.1038/srep15427
URL
https://doi.org/10.1038/srep15427
Keywords
analytical chemistry imaging studies

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.