Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons

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ID: 270320
2002
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Abstract
Reactions of [Fe(TPFPP)] (TPFPP = meso-tetrakis(pentafluorophenyl)porphyrinato dianion) with diazo compounds N(2)C(Ph)R (R = Ph, CO(2)Et, CO(2)CH(2)CH=CH(2)) afforded [Fe(TPFPP)(C(Ph)R)] (R = Ph (1), CO(2)Et (2), CO(2)CH(2)CH=CH(2) (3)) in 65-70% yields. Treatment of 1 with N-methylimidazole (MeIm) …
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Authors Li Y;Huang JS;Zhou ZY;Che CM;You XZ;;
Journal Journal of the American Chemical Society
Year 2002
DOI
DOI not found
URL
http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=PubMed&dopt=Abstract&list_uids=12405847
Keywords
National Center for Biotechnology Information NCBI NLM MEDLINE Molecular pubmed abstract nih national institutes of health national library of medicine models research support non-u.s. gov't Methane / chemistry* molecular structure yan li x-ray iron / chemistry* porphyrins / chemistry* methane / analogs & derivatives* crystallography pmid:12405847 doi:10.1021/ja020391c jie-sheng huang xiao-zeng you carbon / chemistry ferric compounds / chemistry hydrocarbons / chemistry* metalloporphyrins / chemistry methane / isolation & purification porphyrins / isolation & purification

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