Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme - Nature Catalysis

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2018
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Abstract
A haem–carbenoid has been proposed to be involved in abiological enzymatic reactions. Now, Hilvert and co-workers provide crystallographic evidence for a haem–carbenoid intermediate as the reactive species in an olefin cyclopropanation reaction catalysed by an artificial metalloenzyme.
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Authors Hayashi, Takahiro;Tinzl, Matthias;Mori, Takahiro;Krengel, Ute;Proppe, Jonny;Soetbeer, Janne;Klose, Daniel;Jeschke, Gunnar;Reiher, Markus;Hilvert, Donald;Hayashi, Takahiro;Tinzl, Matthias;Mori, Takahiro;Krengel, Ute;Proppe, Jonny;Soetbeer, Janne;Klose, Daniel;Jeschke, Gunnar;Reiher, Markus;Hilvert, Donald;
Journal nature catalysis
Year 2018
DOI
doi:10.1038/s41929-018-0105-6
URL
https://dx.doi.org/10.1038/s41929-018-0105-6##auth-Matthias-Tinzl
Keywords
Biocatalysis X-ray crystallography enzymes iron enzyme mechanisms

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