Capture and characterization of a reactive haemâcarbenoid complex in an artificial metalloenzyme - Nature Catalysis
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ID: 270186
2018
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Abstract
A haemâcarbenoid has been proposed to be involved in abiological enzymatic reactions. Now, Hilvert and co-workers provide crystallographic evidence for a haemâcarbenoid intermediate as the reactive species in an olefin cyclopropanation reaction catalysed by an artificial metalloenzyme.
| Reference Key |
takahiro2018naturecapture
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| Authors | Hayashi, Takahiro;Tinzl, Matthias;Mori, Takahiro;Krengel, Ute;Proppe, Jonny;Soetbeer, Janne;Klose, Daniel;Jeschke, Gunnar;Reiher, Markus;Hilvert, Donald;Hayashi, Takahiro;Tinzl, Matthias;Mori, Takahiro;Krengel, Ute;Proppe, Jonny;Soetbeer, Janne;Klose, Daniel;Jeschke, Gunnar;Reiher, Markus;Hilvert, Donald; |
| Journal | nature catalysis |
| Year | 2018 |
| DOI |
doi:10.1038/s41929-018-0105-6
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