Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand

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ID: 268263
2015
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Abstract
Iron porphyrin carbenes (IPCs) are important intermediates in various chemical reactions catalyzed by iron porphyrins and engineered heme proteins, as well as in the metabolism of various xenobiotics by cytochrome P450. However, there are no prior theoretical reports to help understand their formati …
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Authors Khade RL;Zhang Y;;
Journal Journal of the American Chemical Society
Year 2015
DOI
DOI not found
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http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=PubMed&dopt=Abstract&list_uids=26067900
Keywords
catalysis National Center for Biotechnology Information NCBI NLM MEDLINE Molecular pubmed abstract nih national institutes of health national library of medicine Thermodynamics models research support u.s. gov't non-p.h.s. N.I.H. Extramural ligands yong zhang methane / metabolism hemeproteins / metabolism pmid:26067900 pmc4482416 doi:10.1021/jacs.5b03437 rahul l khade biocatalysis cytochrome p-450 enzyme system / metabolism iron compounds / chemistry* iron compounds / metabolism metalloporphyrins / chemistry* metalloporphyrins / metabolism methane / analogs & derivatives* methane / chemistry

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