Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme - Nature Catalysis

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ID: 267715
2018
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Abstract
A haem–carbenoid has been proposed to be involved in abiological enzymatic reactions. Now, Hilvert and co-workers provide crystallographic evidence for a haem–carbenoid intermediate as the reactive species in an olefin cyclopropanation reaction catalysed by an artificial metalloenzyme.
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Authors Takahiro Hayashi;Matthias Tinzl;Takahiro Mori;Ute Krengel;Jonny Proppe;Janne Soetbeer;Daniel Klose;Gunnar Jeschke;Markus Reiher;Donald Hilvert;Takahiro Hayashi;Matthias Tinzl;Takahiro Mori;Ute Krengel;Jonny Proppe;Janne Soetbeer;Daniel Klose;Gunnar Jeschke;Markus Reiher;Donald Hilvert;
Journal nature catalysis
Year 2018
DOI
doi:10.1038/s41929-018-0105-6
URL
https://dx.doi.org/10.1038/s41929-018-0105-6##auth-Daniel-Klose
Keywords
Biocatalysis X-ray crystallography enzymes iron enzyme mechanisms

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