Re(I) derivatives functionalised with thioether crowns containing the 1,10-phenanthroline subunit as a new class of chemosensors.

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ID: 2658
2015
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Abstract
A series of luminescent fac-[Re(CO)3(L)(NN)](+) complexes, where L is a pyridine or an imidazole and NN is the 1,10-phenanthroline subunit of mixed donor pentadentate thioether crowns have been synthesised and their luminescence properties have been analysed. Then, heterometallic Re(i)/Au(i) complexes, with the Au(i) fragment bonded directly to the imidazole ligand, and heterometallic Re(i)/Ag(i) complexes, with the silver fragment coordinating the S-donor thioether linker of the rings have also been prepared. Analysis of their luminescence properties showed a considerable blue shift of the emission maxima for the Re(i)/Ag(i) derivatives, upon coordination of the silver centre to the S-donor atoms of the aliphatic chain of the macrocyclic units.
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casula2015reidalton Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Casula, Arianna;Nairi, Valentina;Fernández-Moreira, Vanesa;Laguna, Antonio;Lippolis, Vito;Garau, Alessandra;Gimeno, M Concepción;
Journal Dalton transactions (Cambridge, England : 2003)
Year 2015
DOI
10.1039/c5dt02723c
URL
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