Efficient Use of Photons in Photoredox/Enamine Dual Catalysis with a Peptide-Bridged Flavin-Amine Hybrid.

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ID: 26453
2019
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Abstract
An isoalloxazine (flavin) ring system and a secondary amine have been integrated through a short peptide linker with the aim of using photons as efficiently as possible in photoredox/enamine dual catalysis. We herein report a peptide-bridged flavin-amine hybrid that can catalyze α-oxyamination of aldehydes with TEMPO under weak blue light irradiation to achieve an extremely high quantum yield of reaction (Φ = 0.80).
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tagami2019efficientorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tagami, Takuma;Arakawa, Yukihiro;Minagawa, Keiji;Imada, Yasushi;
Journal Organic letters
Year 2019
DOI
10.1021/acs.orglett.9b02567
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