High iso Aldehyde Selectivity in the Hydroformylation of Short-Chain Alkenes.

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ID: 263115
2019
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Abstract
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.
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Authors Iu, Leo;Fuentes, José A;Janka, Mesfin E;Fontenot, Kevin J;Clarke, Matthew L;
Journal Angewandte Chemie (International ed. in English)
Year 2019
DOI
10.1002/anie.201811888
URL
Keywords
rhodium enantioselective catalysis fluorinated solvents hydroformylation phosphorus ligands

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