Cobalt(II)[salen]-Catalyzed Selective Aerobic Oxidative Cross-Coupling between Electron-Rich Phenols and 2-Naphthols.
Clicks: 124
ID: 263113
2019
Article Quality & Performance Metrics
Overall Quality
Improving Quality
0.0
/100
Combines engagement data with AI-assessed academic quality
Reader Engagement
Emerging Content
30.0
/100
123 views
16 readers
Trending
AI Quality Assessment
Not analyzed
Abstract
A selectivity-driven catalyst design approach was adopted to address chemoselectivity issues in the oxidative coupling of phenols. This approach was utilized for developing a Co(II)[salen]-catalyzed aerobic oxidative cross-coupling of phenols in a recyclable 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) solvent. The waste-free conditions offer a sustainable entry to nonsymmetric biphenols via a mechanistic scheme that involves coupling of a liberated phenoxyl radical with a ligated 2-naphthoxyl radical.
Abstract Quality Issue:
This abstract appears to be incomplete or contains metadata (67 words).
Try re-searching for a better abstract.
| Reference Key |
reiss2019cobaltiisalencatalyzedthe
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | Reiss, Hagai;Shalit, Hadas;Vershinin, Vlada;More, Nagnath Yadav;Forckosh, Hagit;Pappo, Doron; |
| Journal | The Journal of organic chemistry |
| Year | 2019 |
| DOI |
10.1021/acs.joc.9b00822
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.