Synthesis of Electron-Deficient Chiral Biphenols and Their Applications in Catalytic Asymmetric Reactions.

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ID: 263108
2020
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Abstract
The axially chiral biphenols are known as a broadly applicable chiral source. However, only a few electron-deficient ones have been reported to date. In the present study, chiral biphenols having several electron-withdrawing groups have been designed, and a facile synthetic route from readily available reagents has been developed. Newly synthesized chiral electron-deficient biphenols and biphenol-derived chiral Brønsted acids functioned as effective catalysts for several catalytic asymmetric reactions.
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yasumoto2020synthesisthe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Yasumoto, Kento;Kano, Taichi;Maruoka, Keiji;
Journal The Journal of organic chemistry
Year 2020
DOI
10.1021/acs.joc.0c01116
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