Geopolymer/Zeolite composite materials with adsorptive and photocatalytic properties for dye removal.
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ID: 262321
2020
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Abstract
This study investigated the adsorption capacities and photocatalytic activities of geopolymer-zeolite composite materials by incorporating different amounts of zeolite and TiO2 in a geopolymer matrix for dye removal. Geopolymers with SiO2/Al2O3 molar ratio of 2.5 were synthesized from metakaolin. The geopolymers containing zeolite and TiO2-doped zeolite exhibited similar behavior in terms of mineral compositions, microstructures and chemical frameworks. The compressive strength of geopolymer-zeolite composite materials decreased with increasing amount of zeolite and TiO2-doped zeolite (0-40 wt%) because of the increase in the porosity of composite materials. The maximum methylene blue adsorption capacity and photocatalytic efficiency of the powdered geopolymer composites with 40 wt% TiO2-doped zeolite was 99.1% and was higher than that of the composites with 40 wt% zeolite without TiO2-doping (92.5%). In addition, the geopolymer composites with TiO2-doped zeolite exhibited excellent stability after repeated usage as photocatalysts. The adsorption capacity and photocatalytic activity of pelletized geopolymer composites decreased because of the reduction in their specific surface area.
| Reference Key |
pimraksa2020geopolymerzeoliteplos
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|---|---|
| Authors | Pimraksa, Kedsarin;Setthaya, Naruemon;Thala, Maneerat;Chindaprasirt, Prinya;Murayama, Mitsuhiro; |
| Journal | PloS one |
| Year | 2020 |
| DOI |
10.1371/journal.pone.0241603
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