Evolution of Corrosion Products Formed during the Corrosion of MgZr Alloy in Poral Solutions Extracted from Na-Geopolymers Used as Conditioning Matrix for Nuclear Waste.

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ID: 262316
2020
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Abstract
Geopolymer, a nanoporous aluminosilicate filled with water and ions, has been selected as a potential matrix to encapsulate MgZr alloy fuel cladding. In this study, we investigate the evolution of the corrosion products formed during the corrosion of MgZr in poral solutions extracted from geopolymers with and without NaF as corrosion inhibitor. Using various characterization techniques such as Scanning Electron and Scanning Transmission Electron Microscopies coupled to Energy Dispersive X-ray spectroscopy and Grazing Incidence X-ray Diffraction, we show that the amounts of dissolved silica and fluoride species in solution are the key parameters driving the nature of corrosion products and probably their passivating properties regarding MgZr corrosion.
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boubon2020evolutionmaterials Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Boubon, Rémi;Deschanels, Xavier;Cabié, Martiane;Rébiscoul, Diane;
Journal Materials (Basel, Switzerland)
Year 2020
DOI
E4958
URL
Keywords
X-ray diffraction tem interfaces geopolymer magnesium alloys alkaline corrosion passive film evolution

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