Synthesis of 1,3,3,5,5-Penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-[(1 H -1,2,3-triazol-4-yl)alkoxy]cyclotriphosphazenes
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ID: 261135
2019
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Abstract
Based on 1,3,3,5,5-penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-chlorocyclotriphosphazene, a series of hybrid compounds was obtained by two-step synthesis. In the molecules of the compounds obtained, hydrophobic organic residues are attached to the cyclotriphosphazene nucleus via a linker. A dialkyl substituted 1,2,3-triazole synthesized by click-chemistry methodology from acetylenic cyclotriphosphazene derivatives and organic azides in the presence of Cu(I) can be used as a linker connecting pentadioxolane-substituted phosphazene core. The reaction proceeds regioselectively with the formation of 1,4-disubstituted 1,2,3-triazoles only.
| Reference Key |
morgalyuk2019russiansynthesis
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| Authors | V. P. Morgalyuk;T. S. Strelkova;Yu. N. Kononevich;V. K. Brel;V. P. Morgalyuk;T. S. Strelkova;Yu. N. Kononevich;V. K. Brel; |
| Journal | russian journal of general chemistry |
| Year | 2019 |
| DOI |
doi:10.1134/S1070363219080115
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