New synthesis of trimethylsilyl esters of phosphorus(III) acids

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ID: 260651
2019
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Abstract
A novel synthetically important reaction has been developed for the quick, convenient, and high-yield preparation of trimethylsilyl esters of phosphorus(III) acids, synthetically valuable Michaelis–Arbuzov reaction precursors. Commercially and synthetically available initial compounds used are derivatives of propan-2-ol phosphorylated in the second position capable of long-term storage and available silylating reagents: hexamethyldisilazane, bis(trimethylsilyl)acetamide, and diethyl(trimethylsilyl)amine. Also, a stepwise reaction scheme of the starting compounds with silylating reagents has been proposed.
Reference Key
morgalyuk2019monatsheftenew Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Vasily Morgalyuk;Tatyana Strelkova;Valery Brel;Vasily Morgalyuk;Tatyana Strelkova;Valery Brel;
Journal monatshefte für chemie - chemical monthly
Year 2019
DOI
doi:10.1007/s00706-019-02511-6
URL
https://doi.org/10.1007/s00706-019-02511-6
Keywords
Organic Chemistry inorganic chemistry analytical chemistry physical chemistry general chemistry/food science theoretical and computational chemistry reaction mechanisms phosphorus compounds retro reactions phosphorus(iii) trimethylsilylether

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