New synthesis of trimethylsilyl esters of phosphorus(III) acids

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ID: 260651
2019
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Abstract
A novel synthetically important reaction has been developed for the quick, convenient, and high-yield preparation of trimethylsilyl esters of phosphorus(III) acids, synthetically valuable Michaelis–Arbuzov reaction precursors. Commercially and synthetically available initial compounds used are derivatives of propan-2-ol phosphorylated in the second position capable of long-term storage and available silylating reagents: hexamethyldisilazane, bis(trimethylsilyl)acetamide, and diethyl(trimethylsilyl)amine. Also, a stepwise reaction scheme of the starting compounds with silylating reagents has been proposed.
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Authors Vasily Morgalyuk;Tatyana Strelkova;Valery Brel;Vasily Morgalyuk;Tatyana Strelkova;Valery Brel;
Journal monatshefte für chemie - chemical monthly
Year 2019
DOI
doi:10.1007/s00706-019-02511-6
URL
https://doi.org/10.1007/s00706-019-02511-6
Keywords
Organic Chemistry inorganic chemistry analytical chemistry physical chemistry general chemistry/food science theoretical and computational chemistry reaction mechanisms phosphorus compounds retro reactions phosphorus(iii) trimethylsilylether

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