efficient, solvent-free oxidation of organic compounds with potassium dichromate in the presence of lewis acids

أكسدة فعالة وخالية من المذيبات للمركبات العضوية باستخدام ثنائي كرومات البوتاسيوم في وجود أحماض لويس

Clicks: 245
ID: 256438
2001
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Abstract
The synthetic utility of potassium dichromate in the presence of Lewis acids under solid phase conditions is described. This reagent efficiently oxidizes alcohols, acyloins, oximes and semicarbazones to their corresponding carbonyl compounds, while trimethylsilyl and tetrahydropyranyl ethers, ethylene acetals and ketals undergo oxidative deprotection to produce carbonyl compounds efficiently.
يُوصَف الاستخدام التخليقي لثنائي كرومات البوتاسيوم في وجود أحماض لويس تحت ظروف الطور الصلب. يُؤكسِد هذا الكاشف بكفاءة الكحولات، والأسيلوينات، والأوكسيمات، والسميكاربازونات إلى مركبات الكربونيل المقابلة لها، في حين تخضع إيثرات ثلاثي ميثيل السيليل ورباعي هيدرو البيران، وأسيتالات الإيثيلين والكيتالات لعملية إزالة الحماية التأكسدية لإنتاج مركبات الكربونيل بكفاءة.
Reference Key
adibi2001moleculesefficient, Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Abol-Hassan Adibi;Majid M. Sadeghi;Iraj Mohammadpoor-Baltork
Journal Journal of ethnopharmacology
Year 2001
DOI
10.3390/61100900
URL
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