synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement
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ID: 256437
2005
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Abstract
Glycosidation of various glycals with furanic alcohols in presence of catalytic amount of ceric(IV) ammonium nitrate under neutral condition or using Lewis acid-catalysed proceeds smoothly to afford the corresponding 2,3-unsaturated glycosides in good yields. In the hexose series predominantly α-D-anomers resulted while β-D-anomers are predominant in the pentose serie.
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| Authors | ;Soro Yaya;Siaka Sorho;Louis Cottier;Gérard Descotes |
| Journal | Experimental physiology |
| Year | 2005 |
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