t-3-benzyl-r-2,c-6-diphenylpiperidin-4-one
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ID: 253455
2016
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Abstract
The asymmetric unit of the title compound, C24H23NO, contains two crystallographically independent molecules (A and B). In both molecules, the piperidine rings adopt a chair conformation and the phenyl rings and the benzyl group substituents are attached equatorially. The dihedral angle between the phenyl rings is 60.80 (10)° in molecule A and 68.43 (9)° in molecule B. The phenyl ring of the benzyl group makes dihedral angles of 76.95 (9) and 42.25 (10)° with the phenyl rings in molecule A, and dihedral angles of 81.38 (11) and 30.19 (11)° in molecule B. In the crystal, the two molecules are linked by N—H...O hydrogen bonds, forming –A–B–A–B– chains along [100]. In addition, five C—H...π interactions are also present, linking the chains to form a three-dimensional structure.
| Reference Key |
arulraj2016iucrdatat-3-benzyl-r-2,c-6-diphenylpiperidin-4-one
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|---|---|
| Authors | ;R. Arulraj;S. Sivakumar;A. Thiruvalluvar;A. Manimekalai |
| Journal | lecture notes in civil engineering |
| Year | 2016 |
| DOI |
10.1107/S2414314616001887
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