cembrane derivatives from the soft corals, sinularia gaweli and sinularia flexibilis
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ID: 251814
2013
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Abstract
A new norcembranoidal diterpene, 1-epi-sinulanorcembranolide A (1), and a new cembranoidal diterpene, flexibilin D (2), were isolated from the soft corals, Sinularia gaweli and Sinularia flexibilis, respectively. The structures of new metabolites 1 and 2 were elucidated by spectroscopic methods, and compound 2 was found to significantly inhibit the accumulation of the pro-inflammatory iNOS and COX-2 proteins of the lipopolysaccharide (LPS)-stimulated RAW264.7 macrophage cells. In addition, S. flexibilis yielded a known cembrane, 5-dehydrosinulariolide (3); the structure, including its absolute stereochemistry, was further confirmed by single-crystal X-ray diffraction analysis.
| Reference Key |
wu2013marinecembrane
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| Authors | ;Yang-Chang Wu;Ping-Jyun Sung;Wei-Hsien Wang;Yu-Wei Chang;Yung-Husan Chen;Wu-Fu Chen;Ting-Jang Lu;Zhi-Hong Wen;Michael Yen-Nan Chiang;Li-Chung Hu;Jui-Hsin Su;Wei-Hsuan Yen |
| Journal | jixie gongcheng xuebao/journal of mechanical engineering |
| Year | 2013 |
| DOI |
10.3390/md11062154
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| URL | |
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