bent dinuclear platinum(ii) halo-bridged carbonyl complexes
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ID: 251662
2011
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Abstract
Crystals of trans-Pt2(μ-X)2X2(CO)2 (X = Br, I) have been grown and their molecular and crystalline structures have been solved by X-ray diffraction methods. In both cases the dinuclear molecules are bent, with a bending angle of 164.6° and 156.5° for the bromide and the iodide, respectively. While the structure of the bromo-derivative is reported here for the first time, a modification of trans-Pt2(μ-I)2I2(CO)2 with planar centrosymmetric molecules is known. This appears to be a rare case of a platinum(II) halo-bridged derivative structurally characterized in both bent and planar forms.
| Reference Key |
marchetti2011moleculesbent
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|---|---|
| Authors | ;Fabio Marchetti;Luca Labella;Daniela Belli Dell'Amico |
| Journal | Journal of ethnopharmacology |
| Year | 2011 |
| DOI |
10.3390/molecules16076082
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| URL | |
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