the missing piece in biosynthesis of amphidinols: first evidence of glycolate as a starter unit in new polyketides from amphidinium carterae
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ID: 251216
2017
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Abstract
Two new members of the amphidinol family, amphidinol A (1) and its 7-sulfate derivative amphidinol B (2), were isolated from a strain of Amphidinium carterae of Lake Fusaro, near Naples (Italy), and chemically identified by spectroscopic and spectrometric methods. Amphidinol A showed antifungal activity against Candida albicans (MIC = 19 µg/mL). Biosynthetic experiments with stable isotope-labelled acetate allowed defining the elongation process in 1. For the first time the use of glycolate as a starter unit in the polyketide biosynthesis of amphidinol metabolites was unambiguously demonstrated.
| Reference Key |
cutignano2017marinethe
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|---|---|
| Authors | ;Adele Cutignano;Genoveffa Nuzzo;Angela Sardo;Angelo Fontana |
| Journal | jixie gongcheng xuebao/journal of mechanical engineering |
| Year | 2017 |
| DOI |
10.3390/md15060157
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| URL | |
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