effect of hydrogen peroxide content on the preparation of peroxotitanate materials for the treatment of radioactive wastewater

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ID: 250537
2016
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Abstract
The modification of peroxotitanate using hydrogen peroxide significantly improved the ion-exchange capacity of titanate materials as sorbents for metal ions contained in a radioactive waste simulant solution. The effects of hydrogen peroxide content (hydrogen peroxide/titanium isopropoxide molar ratios, hereafter expressed as H/T) on the properties of as-prepared titanate synthesized at 130°C and at pH of 6-7, followed by freeze-drying, were investigated. The peroxotitanate materials thus obtained were characterized by XRD, BET, SEM, TEM, EDX, ICP, and Raman spectroscopy. At an H/T ratio of 2, peroxotitanate predominantly exhibited an amorphous structure, with a clearly observed tubular or fibrous structure. Furthermore, peroxotitanate modified at an H/T ratio of 2 exhibited the best ion-exchange capacity of 191 mg g−1 for metal ions contained in a radioactive waste simulant solution. Hence, these peroxotitanate materials are suitable for removing metal ions from wastewater, especially lanthanide ions (Ln3+) and Sr2+.
Reference Key
yang2016journaleffect Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Wein-Duo Yang;Chau Thanh Nam;Jen-Chien Chung;Hsin-Ya Huang
Journal reproductive biology and endocrinology
Year 2016
DOI
10.1155/2016/9540529
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