solventless migratory-insertion reactions of substituted cyclopentadienyl iron complexes induced by electron donor ligands

Clicks: 142
ID: 250067
2009
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Steady

Ranked #46 of 62 articles by views in Experimental physiology

Most read Least read

Bar heights use a square-root scale.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Reaction between solid (C5H5)Fe(CO) 2CH3 and a range of solid phosphine ligands, L (L = PPh3, P(m-CH3C6H4)3, P(p-CH3C6H4)3, P(p-FC6H4)3, P(p-ClC6H4)3, PCy3) occurred in the absence of solvent in the melt phase to give the migratory-insertion products, (C5H5)Fe(CO)(COCH3)(L). The reaction was more rapid with small electron withdrawing ligands. Insertion reaction between (RC5H4)Fe(CO) 2 R’ (R = H, CH3; R’ = CH3, CH2Ph) and gaseous ligands such as SO2 and CO were also studied. The insertion of SO2 occurred readily for all the substrates investigated, but CO insertion did not occur (< 1 %) using the solventless reaction condition.
Reference Key
munyaneza2009bulletin<b>solventless Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Apollinaire Munyaneza, Olalere G. Adeyemi, Neil J. Coville
Are you one of these authors? Claim your profile
Journal Experimental physiology
Year 2009
DOI
DOI not found
URL
http://www.ajol.info/index.php/bcse/article/view/47664
Keywords
migratory-insertionchemistry

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.