the reaction mechanism of acetaldehyde ammoximation to its oxime in the ts-1/h2o2 system

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ID: 248197
2016
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Abstract
A qualitative analysis for the ammoximation of acetaldehyde to its oxime in the TS-1(Titanium Silicalite-1)/H2O2 system was investigated using an in situ infrared spectrometer (ReactIR15). NH3 is first oxidized to NH2OH by TS-1/H2O2; then, CH3CH=NOH forms after NH2OH reacts with CH3CHO. That means the intermediate of this reaction is NH2OH instead of CH3CH=NH. Experiments have been conducted to verify the mechanism, and the results are in good agreement with the infrared findings.
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meng2016catalyststhe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Chaoqun Meng;Suohe Yang;Guangxiang He;Guohua Luo;Xin Xu;Haibo Jin
Journal journal of essential oil research
Year 2016
DOI
10.3390/catal6070109
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