new naphthoquinone terpenoids from marine actinobacterium, streptomyces sp. cnq-509
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ID: 245699
2018
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Abstract
A member of the marine streptomycete clade MAR4, Streptomyces sp. CNQ-509, has genetic potential for the biosynthesis of hybrid isoprenoids and produces several meroterpenoids such as naphterpin, nitropyrrolin and marinophenazine. Our research on the strain CNQ-509 led to the isolation of two new naphterpin derivatives (1 and 2) comprised of naphthoquinone and geranyl moieties along with the known terpenoid, debromomarinone. The two-dimensional structure of these compounds was determined through spectral data analysis using data from NMR, MS and UV spectroscopy. Furthermore, the full structures of 1 and 2 including absolute configurations were unequivocally established by a combination of NMR experiments and chemical modifications.
| Reference Key |
park2018marinenew
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|---|---|
| Authors | ;Jin-Soo Park;Hak Cheol Kwon |
| Journal | jixie gongcheng xuebao/journal of mechanical engineering |
| Year | 2018 |
| DOI |
10.3390/md16030090
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