bis(2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)nickel(ii) bis(perchlorate) hemihydrate

Clicks: 194
ID: 245525
2016
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Steady

Ranked #100 of 203 articles by views in lecture notes in civil engineering

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 203 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
In the title compound, [Ni(C15H11N3)2](ClO4)2·0.5H2O, the Ni2+ cation is coordinated by two terpyridine ligands to form a discrete complex and the coordination polyhedron can be described as a slightly distorted octahedron. It crystallizes as a hemihydrate with two perchlorate anions to compensate the charges. In the crystal, one of the two crystallographically independent perchlorate anions is involved in O—H...O hydrogen bonding to the water molecules, where two inversion-related water molecules link two inversion-related perchlorate anions into a ring with an R42(12) loop. The O-atom position of the water molecule is only half occupied, i.e. only half of the anions are involved in hydrogen bonding. A similar arrangement of two anions is also observed for the second crystallographically independent perchlorate anion but no water molecules are located between the anions. The cationic complex and the perchlorate anions are additionally linked by a number of weak C—H...O hydrogen bonds, forming a three-dimensional supramolecular structure. The crystal structure of the monohydrate of the same complex has been reported [Baker et al. (1995). Aust. J. Chem. 48, 1373–1378].
Reference Key
anderer2016iucrdatabis(2,2:6,2-terpyridine-3n,n,n)nickel(ii) Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Carolin Anderer;Christian Näther;Wolfgang Bensch
Journal lecture notes in civil engineering
Year 2016
DOI
10.1107/S2414314616010099
URL
http://scripts.iucr.org/cgi-bin/paper?S2414314616010099
Keywords
crystal structure hydrogen bondingcrystallography

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.