tandem catalysis of an aldol-‘click’ reaction system within a molecular hydrogel
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2016
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Abstract
A heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent reaction between phenylacetylene, p-nitrobenzaldehyde, and an azide containing a ketone moiety, obtaining the corresponding aldol products in good yields. A possible mechanistic pathway responsible for this unexpected catalytic behavior has been proposed.
| Reference Key |
arajo2016moleculestandem
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|---|---|
| Authors | ;Marco Araújo;Iván Muñoz Capdevila;Santiago Díaz-Oltra;Beatriu Escuder |
| Journal | Journal of ethnopharmacology |
| Year | 2016 |
| DOI |
10.3390/molecules21060744
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| URL | |
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