Relevance of N-nitrosation reactions for secondary amines in nitrate-rich wastewater under UV-C treatment.

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ID: 2444
2019
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Abstract
This study investigated the transformation of secondary amine pharmaceuticals in UV-C/NO and in nitrate-rich wastewater at 254 nm by taking diclofenac, diphenylamine, mefenamic acid and furosemide as probe compounds. The degradation of targeted compounds were positively related to nitrate concentration and mainly caused by the formation of peroxynitrite and related reactive nitrogen species (e.g., nitrogen oxide and nitrogen dioxide radicals). Major transformation products were identified to provide fundamental understanding of the selective oxidation of secondary amine with reactive nitrogen species. UV photolysis, hydroxyl radical oxidation, nitration and nitrosation processes were found to be the most significant transformation pathways. In case of diphenylamine, for which most of the identified intermediates were available as standard, the relative significance of each transformation route could be established, highlighting for the first time the important role of N-nitrosation processes in UV/NO treatment followed by the decomposition of the resulting N-nitroso compounds by an alpha hydroxylation mechanism. This specific transformation pathway was of concern because it constitutes the molecular basis of N-nitrosamine carcinogenicity and may contribute to the increase in effluent genotoxicity under UV-C treatment in addition to the formation of nitrophenols. Hydrogenocarbonate ions at concentration values higher than 300 mg/L appeared to be a protective specie against nitrosation processes due to the formation of carbamate adducts but HO in UV-C/HO could be responsible for an exacerbation of the N-nitrosation pathway due to an addition source of hydroxyl radical in the system. The occurrence of major transformation products of diclofenac was confirmed in nitrate-rich wastewater under UV-C treatment at pilot-scale operation.
Reference Key
brienza2019relevancewater Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Brienza, Monica;Manasfi, Rayana;Chiron, Serge;
Journal Water research
Year 2019
DOI
S0043-1354(19)30568-8
URL
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