syntheses and spectroscopic studies on macrocyclic complexes of dioxomolybdenum(vi) with furil as precursor
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ID: 243561
2012
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Abstract
Due to their biological relevance, molybdenum catalyzed oxygen transfer reactions have great interest. With this view, some dioxomolybdenum(VI) complexes with general formula [MoO2(mac)](acac)2, (where mac = tetraazamacrocyclic ligands derived from condensation of furil with 1,2-ethanediamine or 1,3-propanediamine and their reaction with β-diketones) have been synthesized using dioxometal ion as kinetic template. The prepared complexes have been characterized by electrical conductance, elemental analyses, infrared and electronic data. All the dioxomoly-bdenum(VI) complexes have octahedral geometry with six coordination.
| Reference Key |
rao2012e-journalsyntheses
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|---|---|
| Authors | ;D. P. Rao;H. S. Yadav;A. K. Yadava;Sanjay Singh;U. S. Yadav |
| Journal | Journal of pharmaceutical and biomedical analysis |
| Year | 2012 |
| DOI |
10.1155/2012/205123
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