n-heterocyclic carbene catalyzed synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol
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2015
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Abstract
An organocatalytic protocol for the synthesis of dimethyl carbonate has been developed. Under the catalysis of 5 mol% N-heterocyclic carbenes, ethylene carbonate undergoes transesterification reaction with methanol under very mild reaction conditions, producing dimethyl carbonate with high efficiency. Furthermore, this N-heterocyclic carbene promoted transesterification can be scaled-up easily without lose of the conversion of dimethyl carbonate.
| Reference Key |
du2015journaln-heterocyclic
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|---|---|
| Authors | ;Guang-Fen Du;Hao Guo;Ying Wang;Wen-Juan Li;Wei-Jie Shi;Bin Dai |
| Journal | zaporožskij medicinskij Žurnal |
| Year | 2015 |
| DOI |
10.1016/j.jscs.2014.03.003
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| URL | |
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