impact of lubricant additives on thephysicochemical properties and activity of three‐way catalysts
Clicks: 176
ID: 242266
2016
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This
article has not been analysed, so there is no overall score —
reader engagement is measured and shown alongside.
Reader Engagement
Steady Performance
30.0
/100
176 views
34 readers
AI Quality Assessment
Not analyzed
Readership in this journal
SteadyRanked #71 of 89 articles by views in journal of essential oil research
Most read
Least read
Bar heights use a square-root scale.
Mint this article as an NFT
Not yet mintedCreate a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.
5
SUSD
one-off · no wallet required
Abstract
As alternative lubricant anti‐wear additives are sought to reduce friction and improve overall fuel economy, it is important that these additives are also compatible with current emissions control catalysts. In the present work, an oil‐miscible phosphorous‐containing ionic liquid (IL), trihexyltetradecylphosphonium bis(2‐ethylhexyl) phosphate ([P66614][DEHP]), is evaluated for its impact on three‐way catalysts (TWC) and benchmarked against the industry standard zinc‐dialkyl‐dithio‐phosphate (ZDDP). The TWCs are aged in different scenarios: neat gasoline (no‐additive, or NA), gasoline+ZDDP, and gasoline+IL. The aged samples, along with the as‐received TWC, are characterized through various analytical techniques including catalyst reactivity evaluation in a bench‐flow reactor. The temperatures of 50% conversion (T50) for the ZDDP‐aged TWCs increased by 30, 24, and 25 °C for NO, CO, and C3H6, respectively, compared to the no‐additive case. Although the IL‐aged TWC also increased in T50 for CO and C3H6, it was notably less than ZDDP, 7 and 9 °C, respectively. Additionally, the IL‐aged samples had higher water‐gas‐shift reactivity and oxygen storage capacity than the ZDDP‐aged TWC. Characterization of the aged samples indicated the predominant presence of CePO4 in the ZDDP‐aged TWC aged by ZDDP, while its formation was retarded in the case of IL where higher levels of AlPO4 is observed. Thus, results in this work indicate that the phosphonium‐phosphate IL potentially has less adverse impact on TWC than ZDDP.
| Reference Key |
xie2016catalystsimpact
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | ;Chao Xie;Todd J. Toops;Michael J. Lance;Jun Qu;Michael B. Viola;Samuel A. Lewis;Donovan N. Leonard;Edward W. Hagaman |
| Journal | journal of essential oil research |
| Year | 2016 |
| DOI |
10.3390/catal6040054
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.